You can only use DFS with IE11 in 32 bit mode. We do not yet support 64-bit IE11. Make sure you are in 32-bit mode. If you are in 32-bit mode and are still having issues please contact Ariba Support.
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If you find you still receive the same message ("This feature is disabled. It is available for Internet Explorer 6+ only.") in 32 bit mode, the details below will help;
In IE11 (X86, 32-bit mode), click Tools>Compatibility View Settings
Close all IE11 browsers
Re-open/login to Ariba and DFS can be enabled.
Thanks for your input. Its working fine now.